Stereoselective α-alkylation of carbonyl compounds using 
tricarbonylchromium-complexed benzyl acetates

Reetz, M. T.; Sauerwald, M.

doi:10.1016/0022-328X(90)85221-J

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Stereoselective α-alkylation of carbonyl compounds using tricarbonylchromium-complexed benzyl acetates

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引用

Reetz, M. T., & Sauerwald, M. (1990). Stereoselective α-alkylation of carbonyl compounds using tricarbonylchromium-complexed benzyl acetates. Journal of Organometallic Chemistry, 382(1-2), 121-128. doi:10.1016/0022-328X(90)85221-J.

引用: https://hdl.handle.net/21.11116/0000-000E-7CCD-1

要旨

Secondary benzyl acetates complexed by Cr(CO)₃ react 100% stereoselectively with enolsilanes in the presence of ZnCl₂ in a process which amounts to α-alkylation of carbonyl compounds.