A simple synthetic route to statine and statine analogues

Reetz, M. T.; Drewes, M. W.; Matthews, B. R.; Lennick, K.

doi:10.1039/C39890001474

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A simple synthetic route to statine and statine analogues

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Reetz, M. T., Drewes, M. W., Matthews, B. R., & Lennick, K. (1989). A simple synthetic route to statine and statine analogues. Journal of the Chemical Society, Chemical Communications, 1989(19), 1474-1475. doi:10.1039/C39890001474.

Cite as: https://hdl.handle.net/21.11116/0000-000E-7CE8-2

Abstract

The biologically important amino acid statine, (3S,4S)-4-amino-3-hydroxy-6-methylheptanoic acid, as well as optically active statine analogues, are readily accessible in the ester form by simple reduction of the corresponding N,N-dibenzyl β-keto esters using NaBH₄ followed by deprotection.