Non-chelation-controlled nucleophilic addition to chiral α-siloxyketones

Reetz, Manfred T.; Hüllmann, Michael

doi:10.1039/C39860001600

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Non-chelation-controlled nucleophilic addition to chiral α-siloxyketones

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Reetz, M. T., & Hüllmann, M. (1986). Non-chelation-controlled nucleophilic addition to chiral α-siloxyketones. Journal of the Chemical Society, Chemical Communications, 1986(21), 1600-1602. doi:10.1039/C39860001600.

Cite as: https://hdl.handle.net/21.11116/0000-000E-7E55-6

Abstract

Non-chelation-controlled Grignard-like and aldol additions to O-silyl protected α-hydroxyketones are possible for the first time using titanium reagents of reduced Lewis-acidity.