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Journal Article

Non-chelation-control in nucleophilic additions to chiral α- and β-alkoxy aldehydes

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Citation

Reetz, M. T., & Kesseler, K. (1984). Non-chelation-control in nucleophilic additions to chiral α- and β-alkoxy aldehydes. Journal of the Chemical Society, Chemical Communications, 1984(16), 1079-1080. doi:10.1039/C39840001079.


Cite as: https://hdl.handle.net/21.11116/0000-000E-7FE1-6
Abstract
The addition of two equivalents of gaseous BF3 to to α- and β-alkoxy aldehydes having a centre of chirality at the α-position leads to doubly complexed species which react diastereoselectively with silyl enol ethers and allylsilanes to provide non-chelation-controlled adducts.