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Stereoselective α-alkylation of ketones and esters using chromiumtricarbonyl-complexed benzyl acetates

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Citation

Reetz, M. T., & Sauerwald, M. (1983). Stereoselective α-alkylation of ketones and esters using chromiumtricarbonyl-complexed benzyl acetates. Tetrahedron Letters, 24(28), 2837-2840. doi:10.1016/S0040-4039(00)88037-5.


Cite as: https://hdl.handle.net/21.11116/0000-000E-82F4-B
Abstract
Secondary benzyl acetates complexed by Cr(CO)3 react 100% stereoselectively with silyl enol ethers in the presence of ZnCl2.