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Journal Article

A General Procedure for Intramolecular α-tert-Alkylation of Carbonyl Compounds

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Citation

Reetz, M. T., Chatziiosifidis, I., & Schwellnus, K. (1981). A General Procedure for Intramolecular α-tert-Alkylation of Carbonyl Compounds. Angewandte Chemie, International Edition in English, 20(8), 687-689. doi:10.1002/anie.198106872.


Cite as: https://hdl.handle.net/21.11116/0000-000E-A3CF-1
Abstract
Mono- and bicyclic as well as spirocyclic carbonyl compounds can be prepared by intramolecular tert-alkylation of olefins such as (1) with SnCl4. An O-stannyl derivative and a carbenium ion are probably intermediates in the reaction, which should find application in terpene and steroid syntheses.