Chemoselective and Position Specific Methylation of tert-Alkyl Halides with 
Methyltitanium(IV) Chlorides

Reetz, Manfred T.; Westermann, Jürgen; Steinbach, Rainer

doi:10.1002/anie.198009011

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Chemoselective and Position Specific Methylation of tert-Alkyl Halides with Methyltitanium(IV) Chlorides

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Reetz, M. T., Westermann, J., & Steinbach, R. (1980). Chemoselective and Position Specific Methylation of tert-Alkyl Halides with Methyltitanium(IV) Chlorides. Angewandte Chemie, International Edition in English, 19(11), 901-902. doi:10.1002/anie.198009011.

Cite as: https://hdl.handle.net/21.11116/0000-000E-A59A-A

Abstract

Methylation with methyltitanium reagents promises to have a wide range of application, not least because of its chemoselectivity. In the tert-alkyl chlorides studied, which additonally contained a primary-or sec-alkyl chloride unit or an olefinic double bond, only the tert-C-atom was methylated under favorable conditions.