Facile Hydride Ion Abstraction from Enamines, Allylamines and Imines

Reetz, M. T.; Stephan, W.; Maier, W. F.

doi:10.1080/00397918008062771

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Facile Hydride Ion Abstraction from Enamines, Allylamines and Imines

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引用

Reetz, M. T., Stephan, W., & Maier, W. F. (1980). Facile Hydride Ion Abstraction from Enamines, Allylamines and Imines. Synthetic Communications, 10(11), 867-871. doi:10.1080/00397918008062771.

引用: https://hdl.handle.net/21.11116/0000-000E-A5AA-8

要旨

The conversion of tertiary amines to iminium ions has been accomplished with such oxidants as mercuric acetate or trityl salts². We wish to report that hydride ion abstraction can be applied to enamines, allylamines and imines. Treatment of 1 or 3 with trityl tetrafluoroborate (⊘ = phenyl) affords 2 in yields of 91% and 63%, respectively.