Thermal Rearrangement of Silylmethyl Acetates

Reetz, Manfred T.; Greif, Norbert

doi:10.1002/anie.197707121

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Thermal Rearrangement of Silylmethyl Acetates

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Reetz, M. T., & Greif, N. (1977). Thermal Rearrangement of Silylmethyl Acetates. Angewandte Chemie, International Edition in English, 16(10), 712-713. doi:10.1002/anie.197707121.

Cite as: https://hdl.handle.net/21.11116/0000-000E-A893-E

Abstract

The inverted ylide (2) is postulated as an intermediate of the intramolecular rearrangement of silylmethyl acctates (1), R³=CH₃ or CF₃. A concerted dyotropic or a two-step radical process are ruled out, and an ionic mechanism is unlikely.