Primary and secondary orbital effects in dyotropic rearrangements

Reetz, M. T.

doi:10.1016/0040-4020(73)80163-2

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Primary and secondary orbital effects in dyotropic rearrangements

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Reetz, M. T. (1973). Primary and secondary orbital effects in dyotropic rearrangements. Tetrahedron, 29(14), 2189-2194. doi:10.1016/0040-4020(73)80163-2.

Cite as: https://hdl.handle.net/21.11116/0000-000E-A98F-3

Abstract

A new class of orbital symmetry controlled reactions which involve the simultaneous migration of two σ-bonds is discussed. Analysis of the stereochemical fate of the migrating groups in thermal and photochemical shifts, based on the Woodward-Hoffmann roles and supported by MINDO/2 calculations, is presented.