Tert-butyl hydroperoxide decomposition as a descriptor for liquid-phase 
hydrocarbon oxidation over transition metal oxide-based catalysts: a screening 
study (GH-12158WP)

Büker, Julia; Shang, Jingqi; Angel, Steven; Budiyanto, Eko; Tüysüz, Harun; Wiggers, Hartmut; Schulz, Christof; Grünewald, Marcus; Peng, Baoxiang; Muhler, Martin

doi:10.24820/ark.5550190.p012.158

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Tert-butyl hydroperoxide decomposition as a descriptor for liquid-phase hydrocarbon oxidation over transition metal oxide-based catalysts: a screening study (GH-12158WP)

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Budiyanto, Eko
Research Group Tüysüz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Tüysüz, Harun
Research Group Tüysüz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Büker, J., Shang, J., Angel, S., Budiyanto, E., Tüysüz, H., Wiggers, H., Schulz, C., Grünewald, M., Peng, B., & Muhler, M. (2024). Tert-butyl hydroperoxide decomposition as a descriptor for liquid-phase hydrocarbon oxidation over transition metal oxide-based catalysts: a screening study (GH-12158WP). ARKIVOC, 2024(3):. doi:10.24820/ark.5550190.p012.158.

引用: https://hdl.handle.net/21.11116/0000-000F-2068-8

要旨

Selective oxidation of hydrocarbons with environmentally friendly oxidizing agents is key to a sustainable future. Therefore, the development of heterogeneously catalyzed reactions using oxidants such as molecular oxygen and alkyl hydroperoxides is a promising approach. For the application of these oxidants on a large scale, highly active and selective catalysts must be developed, which requires a rapid screening of a large variety of materials. We report on a method that enables a volumetric quantification of the O₂ amount evolved from the decomposition of alkyl hydroperoxides, which serves as a fast initial screening step for identifying effective catalysts for hydrocarbon oxidation reactions.