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Single chamber Mg/Ca analyses of Globigerinoides ruber for paleo-proxy calibration using femtosecond LA-ICP-MS

MPG-Autoren
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Fischer,  Alexa
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Schiebel,  Ralf
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Jochum,  Klaus Peter
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Heins,  Lena
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Arns,  Anthea I.
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Aardema,  Hedy M.
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Slagter,  Hans
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Calleja,  Maria Ll.
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Levy,  Noy
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Stoll,  Brigitte
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Walter,  David
Multiphase Chemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Weis,  Ulrike
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Repschläger,  Janne
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Haug,  Gerald H.
Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Zitation

Fischer, A., Schiebel, R., Jochum, K. P., Heins, L., Arns, A. I., Aardema, H. M., et al. (2024). Single chamber Mg/Ca analyses of Globigerinoides ruber for paleo-proxy calibration using femtosecond LA-ICP-MS. Scientific Data, 9: 583. doi:10.1038/s41597-024-03402-0.


Zitierlink: https://hdl.handle.net/21.11116/0000-000F-637A-9
Zusammenfassung
Mg/Ca is an independent proxy in paleoceanography to reconstruct past seawater temperature. Femtosecond Laser Ablation Inductively Coupled Plasma Mass Spectrometry (fs-LA-ICP-MS) was employed to determine the Mg/Ca composition of tests (shells) of the planktic foraminifer species Globigerinoides ruber albus (white chromotype) and G. ruber ruber (red/pink chromotype) sampled alive from the temperate to subtropical eastern North Atlantic with the research sailing yacht Eugen Seibold. Mg/Ca data are compared to (i) the measured in-situ temperature of ambient seawater, (ii) average mixed layer temperature, and (iii) sea surface temperature (SST). The pooled mean chamber Mg/Ca from each plankton tow site exhibits a positive relationship with SST. Two chamber-specific calibrations are derived, which are consistent with previous calibration equations for comparable paleo-archives. The results confirm fs-LA-ICP-MS as reliable method for determining Mg/Ca in G. ruber, and both the penultimate and antepenultimate chambers of adult specimens may provide comprehensible Mg/Ca temperatures of the surface ocean.