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Realizing B-site high-entropy air electrode for superior reversible solid oxide cells

MPG-Autoren
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Hu,  Zhiwei
Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Zitation

Xia, Z., Zhang, Y., Xiong, X., Cui, J., Liu, Z., Xi, S., et al. (2024). Realizing B-site high-entropy air electrode for superior reversible solid oxide cells. Applied Catalysis B: Environmental, 357: 124314, pp. 1-10. doi:10.1016/j.apcatb.2024.124314.


Zitierlink: https://hdl.handle.net/21.11116/0000-000F-7BEC-E
Zusammenfassung
The operational efficiency of reversible solid oxide cells (R-SOCs) is hindered by the limited electroactivity and longevity of air electrodes. High-entropy engineering at the B site can reduce the Co content, enhance the compatibility of air electrodes and electrolyte thermal expansion coefficients, and introduce synergistic effects of multi-elements. In this pioneering work, we successfully prepared a single-phase air electrode, PrBa0.8Ca0.2Fe0.4Co0.4Ni0.4Cu0.4Zn0.4O6-δ (HE-PBC-FCNCZ). The cell with HE-PBC-FCNCZ as the air electrode exhibits a peak power density of 1.42 W cm−2 in fuel cell (FC) mode at 700 ℃, demonstrating robust stability. Its remarkable electrochemical performance and stability rank among the top tier of perovskite cathode materials. X-ray absorption near edge structure (XANES) analyses indicated minimal changes in the oxygen content after the stability test compared to PBCC. This study introduces novel B-site high-entropy air electrodes for R-SOCs, featuring both elevated activity and extended durability. © 2024 Elsevier B.V.