Datensatz

Zusammenfassung

A joint theoretical and experimental study on 32 endohedral silafullerane derivatives [X@Si₂₀Y₂₀]⁻ (X=F-I; Y=F-I, H, Me, Et) and Ͳ_h -[Cl@Si₂₀H₁₂Y₈]⁻ (Y=F-I) is presented. First, we evaluated the structure-determining template effect of Cl⁻ in a systematic series of concave silapolyquinane model systems. Second, we investigated the X⁻→Si₂₀ interaction energy (E_int) as a function of X⁻ and Y and found the largest E_int values for electron-withdrawing exohedral substituents Y. Given that X⁻ ions can be considered as Lewis bases and empty Si₂₀Y₂₀ clusters as Lewis acids, we classify our inseparable host–guest complexes [X@Si₂₀Y₂₀]⁻ as “confined Lewis pairs”. Third, ³⁵Cl NMR spectroscopy proved to be highly diagnostic for an experimental assessment of the Cl⁻→Si₂₀ interaction as the paramagnetic shielding and, in turn, δ (³⁵Cl) of the endohedral Cl⁻ ion correlate inversely with E_int. Finally, we disclose the synthesis of [PPN][Cl@Si₂₀Y₂₀] (Y=Me, Et, Br) and provide a thorough characterization of these new silafulleranes.