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Journal Article

One-step synthesis of melem-based supramolecular assemblies and their photocatalytic properties

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Shvalagin,  Vitaliy       
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Markushyna,  Yevheniia       
Aleksandr Savateev, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Piankova,  Diana V.
Nadezda V. Tarakina, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Tarakina,  Nadezda V.       
Nadezda V. Tarakina, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Shvalagin, V., Markushyna, Y., Piankova, D. V., Grape, E. S., Tarakina, N. V., & Savateev, O. (2025). One-step synthesis of melem-based supramolecular assemblies and their photocatalytic properties. ChemPhotoChem, 9(1): e202400255. doi:10.1002/cptc.202400255.


Cite as: https://hdl.handle.net/21.11116/0000-000F-F5D1-0
Abstract
In this work, melem-based supramolecular assemblies were obtained in one step by thermal treatment of melamine in an autoclave in the presence of sodium chloride. The detailed analysis showed that the obtained powder consists of two phases: poorly crystalline Na-PHI flakes and rod-shaped melem hydrate single crystals (several micrometers long and ~300-500 nm wide). Melem hydrate crystals absorb light in the visible range (Eg = 2.7 eV) and demonstrate photocatalytic activity in the reaction of partial oxidation of benzyl alcohol to benzaldehyde by air under visible light with high selectivity for the target product. At 60% conversion of benzyl alcohol, the selectivity of benzaldehyde formation is above 95%.