Metal-Organic Framework–Specific Catalysis

Bengsch, Marco; Neumann, Constanze N.

doi:10.1002/cctc.202402102

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Metal-Organic Framework–Specific Catalysis

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Bengsch, Marco
Research Group Neumann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bengsch, M., & Neumann, C. N. (2025). Metal-Organic Framework–Specific Catalysis. ChemCatChem, e202402102. doi:10.1002/cctc.202402102.

Cite as: https://hdl.handle.net/21.11116/0000-0010-E41E-C

Abstract

The precision with which atoms can be positioned in 3D space through reticular chemistry imbues metal-organic frameworks (MOFs) with the potential to access catalytic performance beyond what is possible with classical heterogeneous manifolds. In this paper, we highlight illustrative examples in which MOF-based catalysts integrate adsorption and catalysis, optimize cooperation, bypass high-energy intermediates, bring about active site regeneration, stabilize unusual active sites or use extended environment effects in order to break new ground in catalyst design.