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Sex pheromone biosynthesis in Mamestra brassicae l. (Lepidoptera: Noctuidae); stereochemistry of the delta11 desaturation

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Boland, W., Frössl, C., Schöttler, M., & Toth, M. (1993). Sex pheromone biosynthesis in Mamestra brassicae l. (Lepidoptera: Noctuidae); stereochemistry of the delta11 desaturation. Journal of the Chemical Society, Chemical Communications, (14), 1155-1157. doi:10.1039/C39930001155.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-9EDC-1
Abstract
(11S,12R)-and (11R,12S)-[H-2(14)]palmitic acids 1 are converted in the pheromone gland of the moth Mamestra brassicae into the [H-2(11)]- or [H-2(13)]-hexadec-11-enyl acetates 2 by a formal syn-elimination of the C(11)-H(R) and C(12)-H(R) hydrogen atoms