Stereochemical studies on homoterpene biosynthesis in higher plants; 
mechanistic, phylogenetic, and ecological aspects

Gaebler, A.; Boland, W.; Preiss, U.; Simon, H.

doi:10.1002/hlca.19910740820

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Stereochemical studies on homoterpene biosynthesis in higher plants; mechanistic, phylogenetic, and ecological aspects

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Gaebler, A., Boland, W., Preiss, U., & Simon, H. (1991). Stereochemical studies on homoterpene biosynthesis in higher plants; mechanistic, phylogenetic, and ecological aspects. Helvetica Chimica Acta, 74(8), 1773-1789. doi:10.1002/hlca.19910740820.

引用: https://hdl.handle.net/11858/00-001M-0000-0012-A02A-5

要旨

In higher plants, the two homoterpenes 4,8-dimethylnona-1,3,7-triene (1) and 4,8,12-trimethyltrideca-1,3,7,11-tetraene (2) originate from nerolidol (3) or geranyllinalool (4) by an oxidative cleavage of their C-skeletons. The reaction proceeds with excl