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Biosynthesis of sex pheromones in moths: stereochemistry of fatty alcohol oxidation in Manduca sexta

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Hoskovec,  M.
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Svatoš,  Aleš
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Boland,  Wilhelm
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Citation

Hoskovec, M., Luxova, A., Svatoš, A., & Boland, W. (2002). Biosynthesis of sex pheromones in moths: stereochemistry of fatty alcohol oxidation in Manduca sexta. Tetrahedron, 58(45), 9193-9201. doi:10.1016/S0040-4020(02)01199-7.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A0DF-F
Abstract
Six chiral deuterium labelled metabolic probes, (R) and (S)- enantiomers of [1, 10, 10-H-2(3)]-hexadecan-1-ol, (11E)- [1,10,10-H-2(3)]-hexadec-11-en-1-ol and (11Z)-[1, 10, 10-H- 2(3)]-hexadec-11-en-1-ol, were synthesized to examine the stereospecificity