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(E)-selective alkylidenation of aldehydes with reagents derived from alpha-acetoxy bromides, zinc and crcl3

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Knecht, M., & Boland, W. (1993). (E)-selective alkylidenation of aldehydes with reagents derived from alpha-acetoxy bromides, zinc and crcl3. Synlett, (11), 837-838.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A122-D
Abstract
Reagents, prepared from the alpha-acetoxy bromides 2a-d, zinc dust and CrCl3 in THF in the presence of a donor ligand like dimethylformamide, give selectively (E)-alkenes 3a-j upon reaction with aldehydes 1a-f. [References: 13]