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Highly efficient one-pot double-Wittig approach to unsymmetrical (1Z,4Z,7Z)-homoconjugated trienes

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Pohnert,  G.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Boland,  W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Pohnert, G., & Boland, W. (2000). Highly efficient one-pot double-Wittig approach to unsymmetrical (1Z,4Z,7Z)-homoconjugated trienes. European Journal of Organic Chemistry, 200(9), 1821-1826. doi:10.1002/(SICI)1099-0690(200005)2000:9<1821:AID-EJOC1821>3.0.CO;2-U.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A2D2-A
Abstract
We describe a novel one-pot double-Wittig approach towards unsymmetrically substituted skipped trienes using the symmetrical (Z)-hex-3-ene-1,6-bis(triphenylphosphonium iodide) (2) as key reagent. Double alkenylation of the corresponding bis(ylide) 3 wit