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Efficient synthesis of isotopically pure [O-18]-epoxides using molecular oxygen

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Boland,  W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Schöttler, M., & Boland, W. (1997). Efficient synthesis of isotopically pure [O-18]-epoxides using molecular oxygen. Synlett, (1), 91.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A343-6
Abstract
High yields of isotopically pure [O-18]-epoxides are obtained from alkenes and O-18(2) gas in the presence of isobutyraldehyde (Kaneda epoxidation). Unlike peracids, the system allows the selective epoxidation of the double bond in a keto-alkene without