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Stereoselective syntheses of deuterium labelled marmesins; valuable metabolic probes for mechanistic studies in furanocoumarin biosynthesis

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Boland,  Wilhelm
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Citation

Stanjek, V., Miksch, M., & Boland, W. (1997). Stereoselective syntheses of deuterium labelled marmesins; valuable metabolic probes for mechanistic studies in furanocoumarin biosynthesis. Tetrahedron, 53(52), 17699-17710. doi:10.1016/S0040-4020(97)10237-X.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A3A7-4
Abstract
Stereoselective syntheses of deuterium labelled marmesins 3a-3c as metabolic probes for bi synthetic studies are described. Starting from iodo-umbelliferone (5), the title compounds were readily available by copper catalysed alkylation-cyclisation and s