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Biosynthesis of anthecotuloide, an irregular sesquiterpene lactone from Anthemis cotula L. (Asteraceae) via a non-farnesyl diphosphate route

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Andersson,  S.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Boland,  W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Van Klinik, J., Becker, H., Andersson, S., & Boland, W. (2003). Biosynthesis of anthecotuloide, an irregular sesquiterpene lactone from Anthemis cotula L. (Asteraceae) via a non-farnesyl diphosphate route. Organic & Biomolecular Chemistry, 1(9), 1503-1508. doi:10.1039/b300877k.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A416-4
Abstract
Retrobiosynthetic analysis of the allergenic sesquiterpene lactone, anthecotuloide, suggested that this natural product could be formed either by head to head condensation of geranyl diphosphate with dimethylallyl diphosphate, or from farnesyl diphospha