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Absolute Configuration and Synthesis of Dextro Caudoxirene the Gamete-Releasing and Gamete-Attracting Pheromone of the Brown Alga Perithalia-Caudata Phaeophyceae

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Citation

Wirth, D., Boland, W., & Mueller, D. G. (1992). Absolute Configuration and Synthesis of Dextro Caudoxirene the Gamete-Releasing and Gamete-Attracting Pheromone of the Brown Alga Perithalia-Caudata Phaeophyceae. Helvetica Chimica Acta, 75(3), 751-758.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A472-1
Abstract
The absolute configuration of the gamete-releasing and -attracting pheromone 2-vinyl-3-(5'-vinylcyclopent-2'-enyl)oxirane (= (+)-caudoxirene; (+)-1) of the marine brown alga Perithalia caudata is established as (2R,3R,1'S,5'S). Highly diastereoselective