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Protonation of a neutral (S)-beta-bisabolene intermediate is involved in (S)-beta-macrocarpene formation by the maize sesquiterpene synthases TPS6 and TPS11

MPS-Authors
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Köllner,  T. G.
Department of Biochemistry, MPI for Chemical Ecology, Max Planck Society;

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Li,  S.
Department of Biochemistry, MPI for Chemical Ecology, Max Planck Society;

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Svatos,  A.
Research Group Mass Spectrometry, MPI for Chemical Ecology, Max Planck Society;

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Schneider,  B.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Gershenzon,  J.
Department of Biochemistry, MPI for Chemical Ecology, Max Planck Society;

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Degenhardt,  J.
Department of Biochemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Köllner, T. G., Schnee, C., Li, S., Svatos, A., Schneider, B., Gershenzon, J., et al. (2008). Protonation of a neutral (S)-beta-bisabolene intermediate is involved in (S)-beta-macrocarpene formation by the maize sesquiterpene synthases TPS6 and TPS11. The Journal of Biological Chemistry, 283(30), 20779-20788. doi:10.1074/jbc.M802682200.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A6A1-9
Abstract
Terpene synthases are responsible for the large diversity of terpene carbon skeletons found in plants. The unique, carbocationic reaction mechanism of these enzymes can form multiple products from a single prenyl diphosphate substrate. Two maize genes w