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Biosynthesis of defensive allomones in leaf beetle larvae: Stereochemistry of salicylalcohol oxidation in Phratora vitellinae and comparison of enzyme substrate and stereospecificity with alcohol oxidases from several iridoid producing leaf beetles

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Oldham,  N. J.
Research Group Mass Spectrometry, MPI for Chemical Ecology, Max Planck Society;

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Boland,  W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Veith, M., Oldham, N. J., Dettner, K., Pasteels, J. M., & Boland, W. (1997). Biosynthesis of defensive allomones in leaf beetle larvae: Stereochemistry of salicylalcohol oxidation in Phratora vitellinae and comparison of enzyme substrate and stereospecificity with alcohol oxidases from several iridoid producing leaf beetles. Journal of Chemical Ecology, 23(2), 429-443. doi:10.1023/B:JOEC.0000006369.26490.c6.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-B325-9
Abstract
(7S)-[H-2(5)]-Salicylalcohol (3) and (7R)-[H-2(1)]- salicylalcohol (5) have been synthesized in order to examine the stereospecificity of salicylalcohol oxidase from the defensive secretion of the salicylaldehyde-producing leaf beetle Phratora vitellina