An unexpected ion-molecule adduct in negative-ion collision-induced 
decomposition ion-trap mass spectra of halogenated benzoic acids

Attygalle, A. B.; Kharbatia, N.; Bialecki, J.; Ruzicka, J.; Svatos, A.; Stauber, E. J.

doi:10.1002/rcm.2582

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An unexpected ion-molecule adduct in negative-ion collision-induced decomposition ion-trap mass spectra of halogenated benzoic acids

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Svatos, A.
Research Group Mass Spectrometry, MPI for Chemical Ecology, Max Planck Society;

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Stauber, E. J.
Research Group Mass Spectrometry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Attygalle, A. B., Kharbatia, N., Bialecki, J., Ruzicka, J., Svatos, A., & Stauber, E. J. (2006). An unexpected ion-molecule adduct in negative-ion collision-induced decomposition ion-trap mass spectra of halogenated benzoic acids. Rapid Communications in Mass Spectrometry, 20(15), 2265-2270. doi:10.1002/rcm.2582.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-B44C-9

Abstract

The ion observed at m/z 145 when product ion spectra of iodobenzoate anions are recorded using ion-trap mass spectrometers corresponds to the adduct ion [I(H2O)](-). The elements of water required for the formation of this adduct do not originate from t