English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

A simple kinetic model of preferential solvation in binary mixtures

MPS-Authors
/persons/resource/persons15634

Petrov,  N. K.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for biophysical chemistry, Max Planck Society;

/persons/resource/persons16024

Wiessner,  A.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

/persons/resource/persons15854

Staerk,  H.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)

16912.pdf
(Publisher version), 0B

Supplementary Material (public)
There is no public supplementary material available
Citation

Petrov, N. K., Wiessner, A., & Staerk, H. (2001). A simple kinetic model of preferential solvation in binary mixtures. Chemical Physics Letters, 349(5-6), 517-520. Retrieved from http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TFN-44D4R1P-9-1H&_cdi=5231&_user=38661&_pii=S0009261401012519&_origin=search&_coverDate=12%2F07%2F2001&_sk=996509994&view=c&wchp=dGLbVlW-zSkzV&md5=82038f4bcab429d095eccccd0c281443&ie=/sdarticle.pdf.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-F504-1
Abstract
Based on experimental data a kinetic model is presented that adequately describes the main features of preferential solvation of a charge-transfer dipole in binary mixtures. 8- (N,N-dimethylamino)-11H-indeno[2,1-a]pyrene is used as fluorescent probe in toluene/DMSO mixtures. The observed saturation behavior can be understood in terms of microclusters of polar molecules surrounding the solute dipolar species. In such an approach, the size of the microclusters is mainly determined by interfacial surface tension. (C) 2001 Published by Elsevier Science B.V.