Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis 
of R-1-phenyl ethyl acetate

Sahin, Serap; Mäki-Arvela, Päivi; Tessonnier, Jean-Philippe; Villa, Alberto; Shao, Lidong; Su, Dang Sheng; Schlögl, Robert; Salmi, Tapio; Murzin, Dimitri Yu.

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Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

MPS-Authors

/persons/resource/persons22164

Tessonnier, Jean-Philippe
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22199

Villa, Alberto
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22107

Shao, Lidong
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22148

Su, Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22071

Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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引用

Sahin, S., Mäki-Arvela, P., Tessonnier, J.-P., Villa, A., Shao, L., Su, D. S., Schlögl, R., Salmi, T., & Murzin, D. Y. (2010). Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. In E., Gaigneaux, & M., Devillers (Eds.), Scientific Bases for the Preparation of Heterogeneous Catalysts: Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010 (pp. 283-287). Amsterdam: Elsevier.

引用: https://hdl.handle.net/11858/00-001M-0000-0010-F54E-1

要旨

Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.