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Surface Chemistry of Ag Particles: Identification of Oxide Species by Aberration-Corrected TEM and by DFT Calculations

MPS-Authors
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Su,  Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Jacob,  Timo
Theory, Fritz Haber Institute, Max Planck Society;

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Hansen,  Thomas W.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Wang,  Di
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Su, D. S., Jacob, T., Hansen, T. W., Wang, D., Schlögl, R., Freitag, B., et al. (2008). Surface Chemistry of Ag Particles: Identification of Oxide Species by Aberration-Corrected TEM and by DFT Calculations. Angewandte Chemie International Edition, 47(27), 5005-5008. doi:10.1002/anie.200800406.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0010-FE62-7
Abstract
Edges and steps have been identified as the locations of surface (O2) and subsurface oxygen atoms (O1) on silver particles by means of DTF calculations and aberration-corrected transmission electron microscopy. The experemental technique allows surface features, such as terraces, steps, and edges, to be clearly imaged by eliminating the Fresnel fringes.