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The mechanism of carbonate formation on Pd–Al2O3 catalysts

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Föttinger, K., Schlögl, R., & Rupprechter, G. (2008). The mechanism of carbonate formation on Pd–Al2O3 catalysts. Chemical Communications, (3), 320-322. doi:10.1039/b713161e.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-FF1D-C
Abstract
Vibrational spectroscopic investigations of the adsorption of isotopically labelled and unlabelled CO and CO2 reveal that carbonate formation on Pd–alumina catalysts occurs via an oxygen down reaction of CO with hydroxyl groups on the support, whereas CO dissociation on Pd can be excluded.