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Upper limits for the circular dichroism for the C 1s and O 1s core excitation of methyl oxirane

MPS-Authors
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Prümper,  Georg
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Lischke,  Toralf
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Reinköster,  Axel
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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ID_319381.pdf
(Preprint), 337KB

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Citation

Prümper, G., Lischke, T., Fukuzawa, H., Reinköster, A., & Ueda, K. (2007). Upper limits for the circular dichroism for the C 1s and O 1s core excitation of methyl oxirane. Journal of Physics B: Atomic, Molecular and Optical Physics, 40, 3425-3434. doi:10.1088/0953-4075/40/17/010.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-FFFA-9
Abstract
The circular dichroism (CD) in the total and partial ion yields of methyl-oxirane C₃H₆O was measured at the C 1s and O 1s edges. The difference of the response of the chiral molecule to circularly polarized light with opposite handedness was found to be less than 0.2% for the total ion yield and less than 0.5% for the partial ion yield. Additionally we tried to find a dipole allowed molecular orientation CD effect by analysing the fragmentation in the forward and backward direction. For this effect we found an upper limit of 1–2% for all abundant ionic fragments.