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Journal Article

Formation of regular surface-supported mesostructures with periodicity controlled by chemical reaction rate

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Mikhailov,  Alexander S.
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Locatelli, A., Mentes, T. O., Aballe, L., Mikhailov, A. S., & Kiskinova, M. (2006). Formation of regular surface-supported mesostructures with periodicity controlled by chemical reaction rate. Journal of Physical Chemistry B, 110(39), 19108-19111. doi:10.1021/jp065090u.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-0398-A
Abstract
We report a LEEM and XPEEM study of the formation of a variety of stationary two-dimensional metallic and oxygen structures in Au and Au + Pd adlayers on Rh(110) during water formation reaction. They result from chemically frozen spinodal decomposition and are created, preserved, or reversibly modified by tuning the reaction conditions. The wavelength of lamellar structures obtained at intermediate metal coverage is found to obey a power scaling law with respect to the reaction rate.