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Abstract

The bimetallic Pd–Ag model catalysts were prepared by physical vapor deposition on thin alumina films. The morphology and structure of the Pd–Ag particles were studied by STM, XPS, and by TPD and IRAS of CO. The results showed the formation of true alloy particles with Ag segregated at the surface. The addition of Ag first suppresses the most strongly bonded CO on threefold hollow sites of Pd. With further increasing Ag coverage, only isolated Pd atoms surrounded by Ag atoms are likely present on the surface. The results on CO adsorption suggest that the model Pd–Ag system mimics the structure of the real Pd–Ag catalysts.