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Infrared Spectroscopic Investigation of Hydrogen and Acrolein Activation on Ag/SiO2 Hydrogenation Catalysts

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Kröhnert,  Jutta
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Teschner,  Detre
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Knop-Gericke,  Axel
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Jentoft,  Friederike C.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Hohmeyer,  Jens
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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引用

Kröhnert, J., Teschner, D., Knop-Gericke, A., Jentoft, F. C., Schlögl, R., Hohmeyer, J., Bron, M., & Claus, P. (2006). Infrared Spectroscopic Investigation of Hydrogen and Acrolein Activation on Ag/SiO2 Hydrogenation Catalysts. Poster presented at XXXIX. Jahrestreffen Deutscher Katalytiker, Weimar.


引用: https://hdl.handle.net/11858/00-001M-0000-0011-0535-9
要旨
Introduction
Selective hydrogenation of α,β-unsaturated aldehydes is one route to unsaturated alcohols with the double bond in allylic position, which are important intermediates for the production of fine chemicals, pharmaceuticals and perfumes. Supported Ag or Au are suitable catalysts, and more selective than e.g. Ru or Ni systems [1-3]. Little is known about the adsorption and activation of hydrogen and, e.g., acrolein on silver, and possible effects of the support. Here we use infrared spectroscopy to follow the interaction of the individual reactants with Ag supported on SiO2.
1. P. Claus, H. Hofmeister, J. Phys. Chem. B 103 (1999) 2766.
2. P. Claus, A. Brückner, C. Mohr, H. Hofmeister, J. Am. Chem. Soc. 122 (2000) 11430.
3. M. Lucas, P. Claus, Chem. Ing. Tech. 77 (2005) 110.