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Preferential CO oxidation in H2 (PROX) on Pt/CeO2 catalyst, high-pressure XPS and in-situ DRIFTS study

MPS-Authors
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Teschner,  Detre
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Vass,  Elaine
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Zafeiratos,  Spiros
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schnörch,  Péter
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Hävecker,  Michael
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Knop-Gericke,  Axel
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Sauer,  Hermann
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Kröhnert,  Jutta
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Jentoft,  Friederike C.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Teschner, D., Vass, E., Zafeiratos, S., Schnörch, P., Hävecker, M., Knop-Gericke, A., et al. (2006). Preferential CO oxidation in H2 (PROX) on Pt/CeO2 catalyst, high-pressure XPS and in-situ DRIFTS study. In K. Godehusen (Ed.), BESSY Annual Report 2005 (pp. 254-256). Berlin: Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung m.b.H. (BESSY).


Cite as: http://hdl.handle.net/11858/00-001M-0000-0011-06CF-9
Abstract
The preferential CO oxidation in H2 (PROX) was investigated on Pt/CeO2 catalyst by high-pressure XPS, in-situ DRIFTS and HRTEM techniques, gaining information on the oxidation states and microstructure of the catalysts, as well as on the surface species present during catalytic turnover. A model is built up explaining mechanistic details of the reaction.