Influence of Storage Atmosphere on Properties and Performance of Sulfated 
Zirconia Isomerization Catalysts

Klose, Barbara S.; Jentoft, Friederike C.; Schlögl, Robert

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Influence of Storage Atmosphere on Properties and Performance of Sulfated Zirconia Isomerization Catalysts

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Klose, Barbara S.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Jentoft, Friederike C.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Zitation

Klose, B. S., Jentoft, F. C., & Schlögl, R. (2005). Influence of Storage Atmosphere on Properties and Performance of Sulfated Zirconia Isomerization Catalysts. Talk presented at EuropaCat-VII – Catalysis: a key to richer and cleaner society. Sofia, Bulgaria. 2005-08-28 - 2005-09-01.

Zitierlink: https://hdl.handle.net/11858/00-001M-0000-0011-07BF-1

Zusammenfassung

Sulfated zirconia (SZ) and Mn-promoted SZ (MnSZ) were aged 6-7 months under three different conditions: in (i) a laboratory cupboard, (ii) air saturated with water vapor at 313 K ("tropical"), and dry Ar atmosphere (glovebox). Samples were investigated by BET, XRD, DRIFTS, and n-butane isomerization. From the same parent compound samples were generated that differed in phase composition (SZ), Mn oxidation state (MnSZ), and water and OH content.