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Optical bands of dodecanuclear compounds H4PVMo11O40*y H2O with Keggin structure. Semiclassical vibronic model

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Melsheimer,  Jörg
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Jentoft,  Friederike C.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Klokishner, S., Melsheimer, J., Jentoft, F. C., & Schlögl, R. (2004). Optical bands of dodecanuclear compounds H4PVMo11O40*y H2O with Keggin structure. Semiclassical vibronic model. Physical Chemistry Chemical Physics, 6(9), 2066-2082. Retrieved from http://www.rsc.org/CFmuscat/intermediate_abstract.cfm?FURL=/ej/CP/2004/b312753b.PDF.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0011-0E01-2
Abstract
The problem of optical spectra of dodecanuclear clusters with the Keggin structure is considered. Charge-transfer and d-d -bands arising from intact and ill-defined species formed on different stages of disintegration of the heteropoly acid H4PVMo11O40y H2O are investigated in detail. On the basis of the performed calculations the transformation of optical spectra of H4PVMo11O40 yH2O under increasing temperature and time on stream is explained.