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Structurally complex molybdenum oxide model catalysts for the selective oxidation of propene

MPG-Autoren
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Othman,  Nur Diana
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Abdullah,  Norli Binti
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Timpe,  Olaf
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Knobl,  Stefan
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Niemeyer,  Dirk
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Wagner,  Jakob
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Su,  Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Zitation

Abd Hamid, S. B., Othman, N. D., Abdullah, N. B., Timpe, O., Knobl, S., Niemeyer, D., et al. (2003). Structurally complex molybdenum oxide model catalysts for the selective oxidation of propene. Topics in Catalysis, 24(1-4), 87-95. doi:10.1023/B:TOCA.0000003080.88144.3d.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-0011-0EF8-7
Zusammenfassung
Controlling the precipitation of molybdenum oxide in aqueous solution is a method to arrive at structurally complex solids suitable as model catalysts for selective oxidation studies. Defect geometries of the orthorhombic MoO3 (ortho-MoO3) structure that are essential for the catalytic function are fabricated as main structural motif and require no heating of the catalyst to the temperature of initial mobility of lattice oxygen. The precipitation parameters are identified and are reviewed for their relevance on the final product properties.