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Journal Article

On the angular distributions in molecular photoionization beyond the dipole approximation

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Grum-Grzhimailo,  Alexei N.
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Grum-Grzhimailo, A. N. (2003). On the angular distributions in molecular photoionization beyond the dipole approximation. Journal of Physics B, 36(12), 2385-2407. doi:10.1088/0953-4075/36/12/301.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-1020-F
Abstract
The theory of angular distributions and angular correlations of photoelectrons and recoil ions in molecular photoionization is reformulated in terms of the density matrix and statistical tensor formalism, which incorporates a full multipole expansion of the radiation field. The dynamical parameters of the angular distributions are expressed in terms of the multipole photoionization amplitudes. Photoionization of linear molecules is analysed in more detail. New possible nondipole effects in the molecular photoionization are outlined.