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The resonant Auger spectra of formic acid, acetaldehyde, acetic acid and methyl formate

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Hergenhahn,  Uwe
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Rüdel,  Andy
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Maier,  Klaus
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Hergenhahn, U., Rüdel, A., Maier, K., Bradshaw, A. M., Fink, R. F., & Wen, A. (2003). The resonant Auger spectra of formic acid, acetaldehyde, acetic acid and methyl formate. Chemical Physics, 289(1), 57-67. doi:10.1016/S0301-0104(02)00795-4.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0011-108E-C
Abstract
We have measured the resonant Auger spectra of four simple organic molecules containing a carbonyl (C=O) group, following excitation of an oxygen 1s electron to an antibonding valence orbital. The full range of final state energies is presented. The spectra are analysed for similarities arising from similar chemical structures within the molecules. An ab initio calculation of the resonant Auger spectrum of the simplest molecule, formic acid, is shown to aid in the interpretation.