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Journal Article

Valence and C 1s core level photoelectron spectra of camphor

MPS-Authors
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Rennie,  Emma E.
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Hergenhahn,  Uwe
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Kugeler,  Oliver
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Lischke,  Toralf
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Marburger,  Simon
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Rennie, E. E., Powis, I., Hergenhahn, U., Kugeler, O., Garcia, G., Lischke, T., et al. (2002). Valence and C 1s core level photoelectron spectra of camphor. Journal of Electron Spectroscopy and Related Phenomena, 125(3), 197-203. doi:10.1016/S0368-2048(02)00140-8.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-13AE-A
Abstract
The valence photoelectron spectrum of camphor has been recorded with 95 eV synchrotron radiation, with better definition than previous He I spectra. The spectrum is interpreted by comparison with these He I results and with the aid of an outer-valence Green's Function calculation of the orbital ionization energies. These calculations closely reproduce the observed vertical ionization energies in the outer valence region. A core level spectrum of the C Is region (hv=357.9 eV) is also presented and reveals a marked shift of the carbonyl carbon relative to all others in the molecule.