The pattern of methylcyclopentane and n-hexane on Rh/Al2O3 in catalytic runs of 
various length

de Oliveira, Karine; Teschner, Detre; Oliviero, Laetitia; Paál, Zoltan

doi:10.1023/A:1014826324289

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The pattern of methylcyclopentane and n-hexane on Rh/Al₂O₃ in catalytic runs of various length

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Teschner, Detre
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

de Oliveira, K., Teschner, D., Oliviero, L., & Paál, Z. (2002). The pattern of methylcyclopentane and n-hexane on Rh/Al₂O₃ in catalytic runs of various length. Reaction Kinetics & Catalysis Letters, 75, 185-191. doi:10.1023/A:1014826324289.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-16D6-1

Abstract

Methylcyclopentane and n-hexane were reacted on a Rh/alumina catalyst in a closed-loop reactor. The product composition was analyzed at different moments of the run. In spite of a slow self-deactivation, the distribution of primary products and the depth of hydrogenolysis showed hardly any dependence on the sampling time in the conversion range of 1.5% and 50%. This is discussed in terms of accumulation of hydrocarbonaceous residues and the low readsorption probability of primary products on rhodium surfa