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Identification of RuO2 as the active phase in CO oxidation on oxygen-rich ruthenium surfaces

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Kim,  Young Dok
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Over,  Herbert
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Ertl,  Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Kim, Y. D., Over, H., Krabbes, G., & Ertl, G. (2001). Identification of RuO2 as the active phase in CO oxidation on oxygen-rich ruthenium surfaces. Topics in Catalysis, 14(1-4), 95-100. doi:10.1023/A:1009063201555.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-19E9-0
Abstract
CO oxidation over ruthenium dioxide (RuO2) dominates the CO/CO2 conversion rate over the catalytically active oxygen-rich Ru(0001) surfaces. In sharp contrast, chemisorbed O overlayers on Ru(0001) (with and without dissolved oxygen) are virtually inactive with respect to CO oxidation.