Au NPs on anionic-exchange resin as catalyst for polyols oxidation in batch and 
fixed bed reactor

Villa, Alberto; Chan Thaw, Carine E.; Prati, Laura

doi:10.1016/j.apcatb.2010.03.017

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Au NPs on anionic-exchange resin as catalyst for polyols oxidation in batch and fixed bed reactor

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Chan Thaw, Carine E.
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
Technische Universität Berlin;

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Citation

Villa, A., Chan Thaw, C. E., & Prati, L. (2010). Au NPs on anionic-exchange resin as catalyst for polyols oxidation in batch and fixed bed reactor. Applied Catalysis B: Environmental, 96(3-4), 541-547. doi:10.1016/j.apcatb.2010.03.017.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-2ABF-9

Abstract

Commercial weak basic anion previous termresinnext term (Dowex M-43) was used as support for gold nanoparticles (previous termAu NPs). Au NPsnext term stabilized by tetrakishydroxypropylphosphonium chloride (THPC) were immobilized on the support (previous termAunext termTHPC/Dowex M-43). In alternative, previous termAu NPsnext term were generated by adsorbing NaAuCl4 on the previous termresinnext term and then reduced by NaBH4 (previous termAunext termads/Dowex M-43). These previous termcatalystsnext term were tested in the liquid phase previous termoxidationnext term of glycerol in a glass previous termbatch reactor: Aunext termTHPC/Dowex M-43 showed better activity than previous termAunext termads/Dowex M-43. The higher activity can be attributed to the smaller previous termAunext term nanoparticles in previous termAunext termTHPC/Dowex M-43 than previous termAunext termads/Dowex M-43. Moreover previous termAunext termTHPC/Dowex M-43 was tested in the glycerol previous termoxidationnext term in a previous termfixed bed reactornext term showing good stability during the reaction time. All the previous termcatalystsnext term have been characterised by TEM, FT-IR and XPS.