Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective 
Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes

Liao, Saihu; List, Benjamin

doi:10.1002/anie.200905332

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes

MPS-Authors

/persons/resource/persons58754

Liao, Saihu
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58764

List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

There is no public supplementary material available

引用

Liao, S., & List, B. (2010). Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes. Angewandte Chemie International Edition, 49(3), 628-631. doi:10.1002/anie.200905332.

引用: https://hdl.handle.net/11858/00-001M-0000-000F-8DB3-E

要旨

Paired up: A highly active and enantioselective ion‐pair epoxidation catalyst, consisting of an achiral MnIII–salen complex and a chiral phosphate counteranion, mediates the epoxidization of a wide range of alkenes with high yields and enantioselectivities (see scheme). The unique role of the counteranion is to stabilize an enantiomorphic conformation of the cationic Mn catalyst.