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Detection of Structural Elements of Different Zeolites in Nucleating Solutions by Electrospray Ionization Mass Spectrometry

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Schaack,  Bernd Bastian
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schrader,  Wolfgang
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth,  Ferdi
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Schaack, B. B., Schrader, W., & Schüth, F. (2008). Detection of Structural Elements of Different Zeolites in Nucleating Solutions by Electrospray Ionization Mass Spectrometry. Angewandte Chemie International Edition, 47(47), 9092-9095. doi:10.1002/anie.200803007.


引用: https://hdl.handle.net/11858/00-001M-0000-000F-9087-8
要旨
Building blocks in solution: Characteristic structural elements of the germanium‐containing zeolites ZSM‐5, polymorph C of zeolite Beta, and zeolite A (see picture) are identified in solution immediately before nucleation. The conditions of the reaction direct the polycondensation of silicate towards specific structures at the solution stage.