date: 2012-11-27T13:31:48Z pdf:PDFVersion: 1.5 pdf:docinfo:title: Electrochemical Membrane Reactors for Sustainable Chlorine Recycling xmp:CreatorTool: PScript5.dll Version 5.2.2 access_permission:can_print_degraded: true subject: Polymer electrolyte membranes have found broad application in a number of processes, being fuel cells, due to energy concerns, the main focus of the scientific community worldwide. Relatively little attention has been paid to the use of these materials in electrochemical production and separation processes. In this review, we put emphasis upon the application of Nafion membranes in electrochemical membrane reactors for chlorine recycling. The performance of such electrochemical reactors can be influenced by a number of factors including the properties of the membrane, which play an important role in reactor optimization. This review discusses the role of Nafion as a membrane, as well as its importance in the catalyst layer for the formation of the so-called three-phase boundary. The influence of an equilibrated medium on the Nafion proton conductivity and Cl? crossover, as well as the influence of the catalyst ink dispersion medium on the Nafion/catalyst self-assembly and its importance for the formation of an ionic conducting network in the catalyst layer are summarized. dc:format: application/pdf; version=1.5 pdf:docinfo:creator_tool: PScript5.dll Version 5.2.2 access_permission:fill_in_form: true pdf:encrypted: false dc:title: Electrochemical Membrane Reactors for Sustainable Chlorine Recycling modified: 2012-11-27T13:31:48Z cp:subject: Polymer electrolyte membranes have found broad application in a number of processes, being fuel cells, due to energy concerns, the main focus of the scientific community worldwide. Relatively little attention has been paid to the use of these materials in electrochemical production and separation processes. In this review, we put emphasis upon the application of Nafion membranes in electrochemical membrane reactors for chlorine recycling. The performance of such electrochemical reactors can be influenced by a number of factors including the properties of the membrane, which play an important role in reactor optimization. This review discusses the role of Nafion as a membrane, as well as its importance in the catalyst layer for the formation of the so-called three-phase boundary. The influence of an equilibrated medium on the Nafion proton conductivity and Cl? crossover, as well as the influence of the catalyst ink dispersion medium on the Nafion/catalyst self-assembly and its importance for the formation of an ionic conducting network in the catalyst layer are summarized. pdf:docinfo:subject: Polymer electrolyte membranes have found broad application in a number of processes, being fuel cells, due to energy concerns, the main focus of the scientific community worldwide. Relatively little attention has been paid to the use of these materials in electrochemical production and separation processes. In this review, we put emphasis upon the application of Nafion membranes in electrochemical membrane reactors for chlorine recycling. The performance of such electrochemical reactors can be influenced by a number of factors including the properties of the membrane, which play an important role in reactor optimization. This review discusses the role of Nafion as a membrane, as well as its importance in the catalyst layer for the formation of the so-called three-phase boundary. The influence of an equilibrated medium on the Nafion proton conductivity and Cl? crossover, as well as the influence of the catalyst ink dispersion medium on the Nafion/catalyst self-assembly and its importance for the formation of an ionic conducting network in the catalyst layer are summarized. pdf:docinfo:creator: Tanja Vidakovic-Koch meta:author: Isai Gonzalez Martinez meta:creation-date: 2012-07-30T09:01:29Z created: 2012-07-30T09:01:29Z access_permission:extract_for_accessibility: true Creation-Date: 2012-07-30T09:01:29Z Author: Isai Gonzalez Martinez producer: Acrobat Distiller 9.2.0 (Windows) pdf:docinfo:producer: Acrobat Distiller 9.2.0 (Windows) pdf:unmappedUnicodeCharsPerPage: 0 dc:description: Polymer electrolyte membranes have found broad application in a number of processes, being fuel cells, due to energy concerns, the main focus of the scientific community worldwide. Relatively little attention has been paid to the use of these materials in electrochemical production and separation processes. In this review, we put emphasis upon the application of Nafion membranes in electrochemical membrane reactors for chlorine recycling. The performance of such electrochemical reactors can be influenced by a number of factors including the properties of the membrane, which play an important role in reactor optimization. This review discusses the role of Nafion as a membrane, as well as its importance in the catalyst layer for the formation of the so-called three-phase boundary. The influence of an equilibrated medium on the Nafion proton conductivity and Cl? crossover, as well as the influence of the catalyst ink dispersion medium on the Nafion/catalyst self-assembly and its importance for the formation of an ionic conducting network in the catalyst layer are summarized. Keywords: polymer electrolyte membrane; Nafion; HCl electrolysis; fuel cell; hydrochloric acid; hydrogen chloride; chlorine; recycling; catalyst layer; three phase boundary; crossover access_permission:modify_annotations: true dc:creator: Isai Gonzalez Martinez description: Polymer electrolyte membranes have found broad application in a number of processes, being fuel cells, due to energy concerns, the main focus of the scientific community worldwide. Relatively little attention has been paid to the use of these materials in electrochemical production and separation processes. In this review, we put emphasis upon the application of Nafion membranes in electrochemical membrane reactors for chlorine recycling. The performance of such electrochemical reactors can be influenced by a number of factors including the properties of the membrane, which play an important role in reactor optimization. This review discusses the role of Nafion as a membrane, as well as its importance in the catalyst layer for the formation of the so-called three-phase boundary. The influence of an equilibrated medium on the Nafion proton conductivity and Cl? crossover, as well as the influence of the catalyst ink dispersion medium on the Nafion/catalyst self-assembly and its importance for the formation of an ionic conducting network in the catalyst layer are summarized. dcterms:created: 2012-07-30T09:01:29Z Last-Modified: 2012-11-27T13:31:48Z dcterms:modified: 2012-11-27T13:31:48Z title: Electrochemical Membrane Reactors for Sustainable Chlorine Recycling xmpMM:DocumentID: uuid:45ea07f3-c720-4422-9001-bc2b58d640f5 Last-Save-Date: 2012-11-27T13:31:48Z pdf:docinfo:keywords: polymer electrolyte membrane; Nafion; HCl electrolysis; fuel cell; hydrochloric acid; hydrogen chloride; chlorine; recycling; catalyst layer; three phase boundary; crossover pdf:docinfo:modified: 2012-11-27T13:31:48Z meta:save-date: 2012-11-27T13:31:48Z Content-Type: application/pdf X-Parsed-By: org.apache.tika.parser.DefaultParser creator: Isai Gonzalez Martinez dc:subject: polymer electrolyte membrane; Nafion; HCl electrolysis; fuel cell; hydrochloric acid; hydrogen chloride; chlorine; recycling; catalyst layer; three phase boundary; crossover access_permission:assemble_document: true xmpTPg:NPages: 19 pdf:charsPerPage: 2257 access_permission:extract_content: true access_permission:can_print: true meta:keyword: polymer electrolyte membrane; Nafion; HCl electrolysis; fuel cell; hydrochloric acid; hydrogen chloride; chlorine; recycling; catalyst layer; three phase boundary; crossover access_permission:can_modify: true pdf:docinfo:created: 2012-07-30T09:01:29Z