date: 2012-06-29T09:45:31Z
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pdf:docinfo:title: catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)]
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dc:description: The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex molecule of formula [Cu2(C18H14Br4N2O2)2]n. One of the CuII ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu-O bond [2.885 (4) A] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. [pi]-[pi] stacking interactions [centroid-centroid distance = 3.783 (4) A] and short interchain Br...Br interactions [3.6142 (12)-3.6797 (12) A] are observed.
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description: The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex molecule of formula [Cu2(C18H14Br4N2O2)2]n. One of the CuII ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu-O bond [2.885 (4) A] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. [pi]-[pi] stacking interactions [centroid-centroid distance = 3.783 (4) A] and short interchain Br...Br interactions [3.6142 (12)-3.6797 (12) A] are observed.
dcterms:created: 2012-06-30T12:00:00Z
Last-Modified: 2012-06-29T09:45:31Z
dcterms:modified: 2012-06-29T09:45:31Z
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title: catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)]
Last-Save-Date: 2012-06-29T09:45:31Z
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dc:title: catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)]
modified: 2012-06-29T09:45:31Z
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meta:creation-date: 2012-06-30T12:00:00Z
created: 2012-06-30T12:00:00Z
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Creation-Date: 2012-06-30T12:00:00Z
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producer: International Union of Crystallography
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pdf:docinfo:producer: International Union of Crystallography
pdf:docinfo:created: 2012-06-30T12:00:00Z